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Algebraic and analytic methods
The quantum harmonic oscillator is one of the most important systems in physics. This module develops both the algebraic method (ladder operators) and the analytic method (Hermite polynomials), derives the energy spectrum, and introduces coherent states — the quantum states closest to classical behavior.
The Hamiltonian of the quantum harmonic oscillator is:
We define the ladder (raising and lowering) operators:
In terms of these operators, the Hamiltonian becomes , where is the number operator. The key commutation relation is .
The number operator has non-negative integer eigenvalues The corresponding eigenstates are called number states. The energy eigenvalues are . The ground state energy is called the zero-point energy.
Hamiltonian
Ladder operators
Hamiltonian in ladder form
Energy eigenvalues
Ladder operator actions
The time-independent Schrodinger equation for the harmonic oscillator is:
It is convenient to introduce the dimensionless variable and the dimensionless energy . The equation becomes:
For large , the term dominates, so the asymptotic behavior is . Only the decaying solution is normalizable.
We factor out the asymptotic behavior by writing . Substituting this into the differential equation gives:
This is the Hermite differential equation. Normalizable solutions exist only when for , which reproduces the quantization condition . The functions are Hermite polynomials.
TISE for harmonic oscillator
Dimensionless equation
Hermite equation
Wave function
The quantum harmonic oscillator. The parabolic potential V(ξ) = ξ²/2 (green) confines the particle. Wave functions ψ_n (blue) are Hermite polynomials modulated by a Gaussian. Energy levels E_n = (n + ½)ℏω are equally spaced. Classical probability (amber dashed) peaks at the turning points where the particle slows down.
Coherent states are eigenstates of the lowering operator: . They can be expanded in the number basis as:
The probability of finding quanta follows a Poisson distribution: . The mean photon number is and the variance is .
Coherent states are minimum-uncertainty states for position and momentum: and , giving . Their expectation values and oscillate exactly like a classical harmonic oscillator.
A coherent state evolves by acquiring a time-dependent phase: . This is why coherent states are called the most classical quantum states.
Coherent state definition
Number state expansion
Poisson distribution
Time evolution
A harmonic oscillator is in the state . Compute , , , , and the uncertainties.
Step 1 — Express and in terms of ladder operators: , .
Step 2 — Compute . . Thus .
Step 3 — Compute . because the diagonal matrix elements vanish and the off-diagonal elements cancel. Thus .
Step 4 — Compute . . Only the number operator terms contribute: . Wait — , so and . Thus .
Step 5 — Compute . .
State
Position expectation
Position squared
Position uncertainty
Papers:
David J. Griffiths, Introduction to Quantum Mechanics, 2nd ed., Chapter 2: Time-Independent Schrodinger Equation (Section 2.3)
1. What is the zero-point energy of the quantum harmonic oscillator?
2. What does the raising operator do to ?
3. What are the Hermite polynomials?
4. What is the photon number distribution for a coherent state?
5. Why are coherent states the most classical quantum states?